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IGSSE research team 'polyisobutene' at the project kickoff in Starnberg

 

Polyisobutene are used in industry in large amounts. Depending on their molecular weight, they are required for rubber production or applied as adhesives, e.g.. More than 100,000 t of highly reactive polyisobutene are produced per year. Thus, efficiency and environmental compatibility are very important tasks.

However, to achieve a high qulity and good productivity, all known production methods require reaction temperatures far below 0  °C and solvents such as methylenchloirde, dichlormethane, or ethene. Recently, a new type of catalysts was developed at TUM (Lst. Für Anorganische Chemie), that allows the production of highly reactive polyisobutene at ambient temperature and in solvents free from chlorine. The tasks of this group are to transfer this method developed on the laboratory scale to the scale of a production reactor, the detection of the underlying chemical reaction mechanisms, and, finally, the further improvement of the method.

Polyisobutenes have numerous industrial applications, e.g. as rubbers, sealants, lubricants and oil additives. For the latter two applications, being the largest end-use markets, polyisobutenes are prduced on a several 100.000 t scale per year. Polyisobutenes applied in mineral oil applications are of low molecular weight. They are industrially produced at temperatures below 0°C, usually with very active but simple inorganic Lewis acid initiators.

At the beginning of the project, a new type of catalysts had been developed at TUM (Lst. für Anorganische Chemie), that allow the production of highly reactive polyisobutene at ambient temper-ature and in non-chlorinated solvents, e.g. toluene. This highly efficient and environmentally friendly method is a promising alternative to the traditional industrial process which has enjoyed considerable longevity since 1938. The tasks of this project are, first, modification and optimization of catalysts system; second, the detection of the underlying chemical reaction mechanisms; last but not least, transfer of the new method developed on the laboratory scale to the scale of a production reactor, which can be applied industrially. Under the joint forces of the groups of Prof. Kühn (Molecular Catal-ysis, TUM), Prof. Bungartz (Scientific Computing, TUM) and Dr. Mühlbach (Solution Polymers, BASF SE), the research topics mentioned above have been extensively investigated and fruitful results are obtained with both academia and industrial importance.

In the molecular catalysis group, more cost efficient and environmentally friendly synthetic methods for existing catalysts, as well as new types of catalysts have been developed. The catalytic activities of the compounds were tested both in university and in industry (BASF SE). In order to be applied industrially, the homogenous catalysts have also been immobilized onto different carrier materials. The computer science group has implemented new tools for turbulent flow simulations as a basis for fast mixing processes that substantially influence the number of reactions observed in a reactor. In addition, the flow solver has been enhanced by a module for the simulation of heat transport. As soon as suitable reactor geometries, flow parameters and chemical reactions terms are available, this software can be used to optimize the reactor prototyping and optimization for the new production methos developed in the group of Prof. Kühn

 

  

01-01-1970
14.02.17

Registration now open: IGSSE Forum 2017

29-31 May 2017, TUM Science and Study Center Raitenhaslach, Burghausen

25.04.17

EuroTech postdoc workshop: Success in academia?

20-22 September 2017, Technical University of Denmark, Lynby Campus

18.04.17

Project team ROLITOS in a German documentary

10 May 2017, 11.30 pm Suedwestrundfunk (TV)

30 May 2017, 10.30 pm Bayerischer Rundfunk (TV)

11.04.17

Apply now: McKinsey 'Forschergeist' symposium

9-11 June 2017, Berlin

For doctoral researchers and postdocs!

10.04.17

Register now: ICMSB 2017

26-28 July 2017, TUM Study and Science Center, Raitenhaslach

14.02.17

Registration now open: IGSSE Forum 2017

29-31 May 2017, TUM Science and Study Center Raitenhaslach, Burghausen

05.06.16

10th IGSSE Forum

Smart cooperation - science and technology in, with and for society

15.12.15

The Science of Cooking

Doctoral Candidates explore the Secrets of a great Dinner

26.11.15

ATUMS@IGSSE

Having heard of a great Canadian Kick-Off Meeting, everyone at IGSSE was thrilled to welcome the...

20.11.15

Breakfast at IGSSE´s

Meet the IGSSE team every other month! All the things IGSSE members wanted to asked but never dared...

13.10.15

Save the Date: Canadian ATUMS Speaker on "Global Science- Global Career"

26. November 2015, 6-8 pm, IAS Faculty Club, Garching Campus

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Wednesday, 10. May 2017
Project team ROLITOS in a German documentary
10 May 2017, 11.30 pm Suedwestrundfunk (TV) 30 May 2017, 10.30 pm Bayerischer Rundfunk (TV)
Wednesday, 17. May 2017
Podiumsdiskussion: Frauenförderung - Quo vadis?
17. Mai 2017, 14- 16 Uhr, Hochschule Weihenstephan-Triesdorf, Weidenbach
Friday, 19. May 2017
Tuesday, 23. May 2017
Monday, 29. May 2017
Registration now open: IGSSE Forum 2017
29-31 May 2017, TUM Science and Study Center Raitenhaslach, Burghausen